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高分子物理:“结构与性能”背后的概念(英文版.原书第三版)

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  • 大小:28.68 MB
  • 语言:中文版
  • 格式: PDF文档
  • 类别:物理学书籍
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关键词:英文   物理   性能   背后   概念
资源简介
高分子物理:“结构与性能”背后的概念(英文版.原书第三版)
作者:(德)斯特罗伯 著
出版时间:2012年版
内容简介
  《高分子物理:“结构与性能”背后的概念(英文版.原书第3版)》对高分子物理的多个领域作了生动而详细的介绍,内容涵盖链构象,高分子溶液,共混物和嵌段共聚物,半晶态聚合物,聚合物网络,聚合物流体等多种体系。作者还使用了大量的数学处理与实验结果,对提出的机理与数学模型进行示例与验证,勾勒出一幅浓墨重彩的高分子物理画卷。《高分子物理:“结构与性能”背后的概念(英文版.原书第3版)》可作为化学化工、材料科学和物理学等专业的本科生和研究生教材,也可供有关领域的专家、学者阅读参考。
目录
出版说明
推荐序
preface(前言)
preface to the first edition/第1版前言
1constitution and architecture of chains/链的组成与构造1
2single chain conformations /单链构象15
2.1rotational isomeric states /旋转异构态15
2.2helices/螺旋19
2.3coils /线团22
2.3.1the ideal chain/理想链26
2.3.2the expanded chain/膨胀链45
2.4the persistent chain/持续链55
2.5the ising chain/ 伊辛链59
3polymer solutions /聚合物溶液69
3.1dilute and semidilute solutions/稀溶液与半稀溶液70
3.1.1osmotic pressure/渗透压71
3.2screening of excluded volume forces/排除体积力的屏蔽82
3.3polyelectrolyte solutions/聚电解质溶液89
3.3.1condensation and screening of charges /电荷的团聚与屏蔽89
3.3.2chain stretching, salt effects and interchainordering/链伸展、盐效应与链间序95
3.3.3osmotic pressure/渗透压100
4polymer blends and block copolymers/共混物与嵌段共聚物105
4.1the flory?huggins treatment of polymermixtures/聚合物混合物的flory?huggins处理方法106
4.1.1phase diagrams: upper and lower miscibilitygap/相图:上临界与下临界混溶间隙117
4.2phase separation mechanisms/相分离机理122
4.3critical fluctuations and spinodaldecomposition/临界涨落与旋节线分解129
4.3.1critical scattering/临界散射132
4.3.2decomposition kinetics/分解动力学143
4.4block copolymer phases/嵌段共聚物的相结构151
4.4.1layered structures/层状结构155
4.4.2pretransitional phenomena/前转变现象157
5the semicrystalline state/半结晶态165
5.1structure characteristics/结构特征167
5.1.1morphological elements /基本形态167
5.1.2structure parameters/结构参数173
5.2kinetics of crystallization and melting/结晶与熔融动力学181
5.3laws for the structure development/结构变化规律190
5.3.1the multistage model/多阶段模型199
5.4mechanisms of secondary crystallization/二级结晶机理205
5.4.1the insertion mode/插层模式208
5.4.2surface crystallization and melting/表面结晶与熔融212
5.5crystallization from oriented melts/取向熔体结晶216
6mechanical and dielectric response/力学与介电响应223
6.1response functions/响应函数224
6.1.1viscoelasticity/粘弹性224
6.1.2orientational polarization/取向极化228
6.1.3general relationships/通用公式229
contents6.2relaxatory modes/松弛模式236
6.2.1single?time relaxation process/单时间松弛过程237
6.2.2retardation and relaxation time spectra/推迟与松弛时间242
6.3specific relaxation processes and flow behavior/具体松弛过程与流动行为245
6.3.1local processes/局部过程246
6.3.2glass?rubber transition and melt flow/玻璃?橡胶转变与熔体流动250
6.3.3the glass transition temperature/玻璃化转变温度269
6.3.4relaxation in partially crystalline systems/半晶体系中的松弛277
7conjugated polymers/共轭聚合物287
7.1electrooptic activity/光电活性289
7.1.1excitons and free charges/激发与自由电荷289
7.1.2electroluminescence/电发光297
7.2effects of doping/掺杂效应302
7.2.1electrical conductivity/电导率302
7.2.2magnetism and reflectivity/磁性与反射率306
8microscopic dynamics/微观运动学313
8.1the fluctuation?dissipation theorem/涨落?耗散原理313
8.2the rouse model/rouse模型317
8.2.1stress relaxation/应力松弛325
8.2.2the dielectric normal mode /介电基准模式330
8.3entanglement effects in polymer melts/聚合物熔体中的缠结效应333
8.3.1the reptation model/爬行模型338
8.4solution viscosities/溶液粘度 343
8.4.1neutral polymers: hydrodynamicinteraction/中性聚合物:流体力学作用344
8.4.2polyelectrolytes: coulomb interaction/聚电解质:静电作用 352
9non?linear mechanics /非线性力学357
9.1rubber elasticity/橡胶弹性361
9.1.1the fixed junction model of ideal rubbers/理想橡胶的固定结点模型364
9.1.2the cauchy strain tensor/ cauchy应变张量371
9.1.3finger?s constitutive equation/ finger本构方程376
9.2swelling of neutral and electrolytic gels/中性与电解质凝胶的溶胀384
9.3non?newtonian melt flow/非牛顿熔体的流动390
9.3.1rheological material functions /流变材料函数391
9.3.2the lodge liquid/ lodge液体398
9.3.3the stress?optical rule/应力?光学规则404
10deformation, yielding and fracture/形变、屈服与断裂415
10.1shear deformation in semicrystallinepolymers/半晶聚合物中的剪切形变418
10.1.1critical strains/临界应变418
10.1.2constituents of the drawing stress/拉伸应力的成分426
10.1.3the mechanics of neck formation/细颈形成机理429
10.1.4fibrillar state of order/纤维化有序态435
10.2crazing/银纹 444
10.3brittle fracture/脆性断裂450
10.3.1linear fracture mechanics /线性断裂力学453
10.3.2the slow mode of crack growth/裂缝生长的缓慢模式455
ascattering experiments/散射实验463
a.1fundamentals/基本概念463
a.1.1basic equations/基本方程464
a.1.2time?resolved scattering experiments/时间分解的散射实验468
a.2absolute intensities/绝对强度471
a.3low angle scattering properties/小角散射性质474
a.3.1guinier?s law/ guinier公式474
a.3.2forward scattering/前散射476
a.4special polymer systems/特种聚合物体系477
a.4.1binary mixtures and block copolymers/二元混合物与嵌段共聚物477
a.4.2two?phase layer systems/两相层状体系484
bglossary of symbols/术语与符号493
cbibliography/参考书目501
references/参考文献505
index/索引
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