应用高分子材料
作者： 王者辉 著
出版时间： 2016年版
内容简介
本书以高分子材料的结构·性能·应用为主线，联系其他材料科学，理论结合实际，介绍了各类高分子材料的基础知识和相关的加工成型方法。全书共分6章，高分子材料科学概述、塑料与增塑剂、高分子材料在汽车工业中的应用、医用高分子材料、高分子材料加工技术、纳米材料与高分子材料的新发展，此外，书末附有高分子材料专业词汇注释。本书阐述了高分子材料的基本理论，同时注重高分子材料科学技术知识的实用性。 《Applied Polymer Materials（应用高分子材料）》可供从事高分子材料专业及其他材料科学的科研和生产技术人员使用。
目录
Chapter 1 Fundamentals of Polymer Science / 1
1.1 Introduction / 1
1.1.1 Writing Formulas for Polymeric Macromolecules / 1
1.1.2 Properties of Macromolecules / 3
1.1.3 Three Factors that Influence the Degree of Crystallinity / 4
1.1.4 Regio and Stereo Isomerization in Macromolecules / 6
1.2 Synthesis of Addition Polymers / 7
1.2.1 Radical Chain-Growth Polymerization / 8
1.2.2 Cationic Chain-Growth Polymerization / 10
1.2.3 Anionic Chain-Growth Polymerization / 10
1.2.4 Ziegler-Natta Catalytic Polymerization / 11
1.3 Copolymers / 12
1.3.1 Addition Copolymerization / 12
1.3.2 Block Copolymerization / 13
1.4 Condensation Polymers / 13
1.4.1 Characteristics of Condensation Polymers / 13
1.4.2 Thermosetting vs. Thermoplastic Polymers / 16
1.5 Structure-Property Relationship / 17
1.5.1 Linearity, Branching and Networking / 17
1.5.2 Molar Cohesion, Polarity and Crystallinity / 18
1.5.3 Role of Molecular Symmetry / 18
1.5.4 Role of Chemical Modification in Effecting Internal Plasticization / 19
1.5.5 Copolymerization and Internal Plasticization / 19
1.5.6 Effect of Inclusion of Flexible Inter-unit Linkages and Rigid Bulky Groups / 19
1.5.7 Effect of Temperature / 21
1.5.8 Survey of Deformation Patterns in the Amorphous State / 21
1.5.9 Transitions and Rubbery and Flow Regions / 22
1.5.10 Property Demand and Polymer Applications / 23
1.6 The Age of Plastics / 25
1.7 The Law of Unintended Consequences / 26
1.8 Recycling and Disposal / 27
1.9 Biodegradable Polymers / 29
Chapter 2 Plastics and Plasticizers / 33
2.1 Plasticizers: an Introduction / 33
2.2 Early Plasticizers / 34
2.3 Theory: Mechanism of Plasticizer Effect on the Polymer / 34
2.4 Phthalate Plasticizers / 35
2.5 The Phthalate Plasticizer Market / 35
2.6 Health Issues in the Use of Phthalate Plasticizers: Are They Safe? / 37
2.6.1 Evidence? / 38
2.6.2 What's Being Done in the Meantime? / 39
2.7 Health or Hype? / 39
2.8 Plastics in Packaging / 40
2.8.1 Introduction / 40
2.8.2 Types of Plastics Used in Packaging / 42
2.8.3 Plastic vs. the Alternatives / 48
2.8.4 Reusing Plastic Packaging / 49
2.8.5 Recycling Plastic Packaging / 49
2.8.6 Conclusion / 51
Chapter 3 Polymer Materials Used in Automobiles / 53
3.1 Introduction / 53
3.2 Uses of Polymer Materials in an Automobile / 53
3.2.1 Fuel Tank / 53
3.2.2 Exterior / 55
3.2.3 Interior / 58
3.2.4 Polymers in Car Engine Manifolds and Power Trains / 59
3.2.5 Conclusion / 60
3.3 Car Tires / 61
3.3.1 Introduction / 61
3.3.2 Tire Production / 62
3.3.3 The Chemistry of Tires / 65
3.3.4 Brass Wire Adhesion / 67
3.3.5 Disposal and Recycling of Used Tires / 69
3.3.6 Tread Separation Problem Overview / 69
3.3.7 Lawsuit Against Firestone and Ford Motor Co. / 71
3.3.8 Conclusion / 72
3.4 Kapton(r) Wiring / 72
3.4.1 Introduction / 72
3.4.2 Properties of Kapton(r) / 74
3.4.3 Uses of Kapton(r) / 74
3.4.4 Degradation of Kapton(r) and Other Polymers / 76
3.4.5 Insulation Requirements for Wires / 77
Chapter 4 Polymer Materials in Medicine / 79
4.1 Introduction / 79
4.2 Polymer Materials in Medicine / 80
4.2.1 A Brief History of Polymer Materials in Medicine / 80
4.2.2 Cellophane / 81
4.2.3 PGA, PLA, and PLGA / 82
4.2.4 Polydimethyl Siloxane (PDMS) / 83
4.2.5 Polyethylene and Poly (methyl methacrylate) (PMMA) / 84
4.2.6 Polytetrafluoroethylene (PTFE) / 84
4.2.7 Polyurethane / 85
4.2.8 Conclusion / 86
4.3 Contact Lens Polymers / 86
4.3.1 The History of Contact Lenses / 87
4.3.2 How Contact Lenses Work / 87
4.3.3 Why Do People Wear Contact Lenses / 88
4.3.4 Biocompatibility and Contact Lens Comfort / 89
4.3.5 Manufacturing of Contact Lenses / 90
4.3.6 Hard Contact Lenses / 91
4.3.7 Soft Contact Lenses / 93
4.3.8 Problems Caused by Contact Lens Use / 94
4.3.9 Conclusion / 95
4.4 Silicone Implants / 95
4.4.1 History / 96
4.4.2 Silicone Implants / 96
4.4.3 Advantages / 97
4.4.4 Disadvantages / 97
4.4.5 Concerns / 99
4.4.6 Companies Involved in the Production of Silicone Breast Implants / 100
4.5 Tablet Coating / 100
4.5.1 Drug Release Paterns / 101
4.5.2 Types of Coatings / 103
4.5.3 Polymers Used for Film-Coatings (Film Formers) / 104
4.5.4 Equipment / 106
4.5.5 The Coating Process / 109
4.5.6 Spray Variables / 112
4.5.7 Formulation of Polymeric Coatings / 116
